動力学分割
動力学分割は、2種類のエナンチオマー反応速度の差を利用してラセミ混合物中のエナンチオマーを分離する方法である。C−Hエン化反応では，一方のエナンチオマーは優先的に試薬と反応し，他方は反応しない。この過程により、出発原料の1つのエナンチオマーが製品に変換され、もう1つのエナンチオマーは不変である。高度な選択性を実現することは高度なエナンチオマー濃縮物を獲得する鍵である。
化学原料を購入する必要がある場合は、 要求情報を送信してください最新の見積りを入手してください。
動力学分割の学術論文
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Enantioselective C-H Olefination of α-Hydroxy and α-Amino Phenylacetic Acids by Kinetic Resolution
関連化学物質
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(S)-2-(4-methoxyphenyl)-2-pivalamidoacetic acid
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Solvent-dependent dynamic kinetic asymmetric transformation/kinetic resolution in molybdenum-catalyzed asymmetric allylic alkylations
関連化学物質
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dimethyl (S)-2-(1-phenylallyl)malonate
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Enzymatic synthesis of optical pure β-nitroalcohols by combining d-aminoacylase-catalyzed nitroaldol reaction and immobilized lipase PS-catalyzed kinetic resolution
関連化学物質
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(R)-2-nitro-1-(4-nitrophenyl)ethyl acetate
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Isothiourea-Catalyzed Acylative Kinetic Resolution of Tertiary α-Hydroxy Esters
関連化学物質
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benzyl 2-cyclohexyl-2-hydroxy-2-phenylacetate
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Kinetic resolution of iodophenylethanols by Candida antarctica lipase and their application for the synthesis of chiral biphenyl compounds
関連化学物質
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Benzenemethanol, 3-iodo-a-methyl-
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Highly selective enzymatic kinetic resolution of primary amines at 80°C: A comparative study of carboxylic acids and their ethyl esters as acyl donors
関連化学物質
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Butanamide, N-(1-methyl-3-phenylpropyl)-, (S)-
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Kinetic resolution of tert-butyl (RS)-3-alkylcyclopentene-1-carboxylates for the synthesis of homochiral 3-alkyl-cispentacin and 3-alkyl-transpentacin derivatives
関連化学物質
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1-Cyclopentene-1-carboxylic acid, 3-(phenylmethyl)-, 1,1-dimethylethyl ester
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Kinetic resolution of 3-hydroxymethylbenzocycloalkanols by selective asymmetric hydrogen-transfer oxidation
関連化学物質
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Butanedioic acid, [(4-methoxyphenyl)methyl]-, 1-methyl ester
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An efficient enantioselective synthesis of (+)-(R,Z)-5-muscenone and (-)-(R)-muscone - An example of a kinetic resolution and enantioconvergent transformation
関連化学物質
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HCl
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5-Cyclohexadecen-1-one, 3-methyl-, (3R)-
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Kinetic resolution in vanadium-catalyzed sulfur oxidation as an efficient route to enantiopure aryl benzyl sulfoxides
関連化学物質
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1-fluoro-4-(4-tolylsulfonylmethyl)benzene
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Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates
関連化学物質
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(5E,3S)-1-phenylpent-3-en-1-ol
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Merging nucleophilic and hydrogen bonding catalysis: An anion binding approach to the kinetic resolution of amines
関連化学物質
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(R)-N-(1-phenylpentyl)benzamide
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A convenient method for the kinetic resolution of racemic 2-hydroxyalkanoates using diphenylacetic anhydride (DPHAA) and a chiral acyl-transfer catalyst
関連化学物質
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benzyl (R)-2-(diphenylacetyloxy)propanoate
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Parallel kinetic resolution of racemic oxazolidinones using quasi-enantiomeric active esters
関連化学物質
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(4S)-4-phenyl-3-[(2R)-2-phenylpropionyl]oxazolidin-2-one
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Different Enzymatic Reactions of an Enantiomeric Pair: Simultaneous Dual Kinetic Resolution of a Keto Ester by Bakers' Yeast
関連化学物質
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(S)-(-)-α-methoxy-α-(trifluoromethyl)pnenylacetyl acid ester of methyl (+)-(1R,2R,3S,5S)-3-hydroxy-7-oxobicyclo<3.3.0>octane-2-carboxylate
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Synthesis of α-alkylated γ-butyrolactones with concomitant anhydride kinetic resolution using a sulfamide-based catalyst
関連化学物質
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(3,5-bis(trifluoromethyl)phenyl)sulfamoyl chloride
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Solvent-free kinetic resolution of primary amines catalyzed by Candida antarctica lipase B: Effect of immobilization and recycling stability
関連化学物質
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2-methoxy-N-[1-(4-fluorophenyl)ethyl]acetamide
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N-octanoyldimethylglycine trifluoroethyl ester, an acyl donor leading to highly enantioselective protease-catalysed kinetic resolution of amines
関連化学物質
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N-(((S)-4-phenylbutan-2-ylcarbamoyl)methyl)octanamide
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Kinetic resolution of racemic disubstituted 1-pyrrolines via asymmetric reduction with a chiral titanocene catalyst
関連化学物質
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2-methyl-5-phenylpyrrolidine
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Kinetic Resolution of Phosphines and Phosphine Oxides with Phosphorus Stereocenters by Hydrolases
関連化学物質
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Phosphine oxide, (2-methoxy-1-naphthalenyl)methylphenyl-, (S)-
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Candida antarctica lipase-B-catalyzed kinetic resolution of 1,3-dialkyl-3-hydroxymethyl oxindoles
関連化学物質
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3-benzyl-5-bromo-1-methylindolin-2-one
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Candida Rugosa lipase-catalyzed kinetic resolution of β-hydroxy- β-arylpropionates and δ-hydroxy-δ-aryl-β-oxo-pentanoates
関連化学物質
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Benzenepropanoic acid, b-(1-oxobutoxy)-, ethyl ester
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Kinetic resolution of 3-hydroxycyclohexanone using different lipases
関連化学物質
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(R)-3-oxocyclohexyl acetate
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A Facile Synthesis of N-Protected Statine and Analogues via a Lipase-Catalyzed Kinetic Resolution
関連化学物質
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(Z)-5-benzylidenepyrrolidine-2,4-dione
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Kinetic resolution of amines by acylation using 3-diacylaminoquinazolin- 4(3H)-ones
関連化学物質
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3-[(2-Methylpropanoyl)amino]-2-[(S)-1-tert-butyldimethylsilyloxy-2-methylpropyl]quinazolin-4(3H)-one
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Biocatalytic N-Alkylation of Amines Using Either Primary Alcohols or Carboxylic Acids via Reductive Aminase Cascades
関連化学物質
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Benzenemethanamine, N-nonylidene-
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Facile lipase catalysed syntheses of (S)-(+)-4-hydroxy-β-ionone and (S)-(+)-4-hydroxy-β-damascone: Chiral flavorants and synthons
関連化学物質
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(S)-(+)-4-hydroxy-β-damascone
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Aminocyclopentadienyl Ruthenium Complexes as Racemization Catalysts for Dynamic Kinetic Resolution of Secondary Alcohols at Ambient Temperature
関連化学物質
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(1R)-acetic acid 1-methyl-3-phenylprop-2-ynyl ester
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Bifunctional Phosphonium Salt Directed Enantioselective Formal [4 + 1] Annulation of Hydroxyl-Substituted para-Quinone Methides with α-Halogenated Ketones
関連化学物質
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1,2-Butanediamine,N1,N1,3-trimethyl-,(2R)-(9CI)
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Ramberg-Backlund rearrangement vs. β-Elimination of haloform from trichloro and trifluoromethyl sulfones
関連化学物質
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Diphenylmethyl-dichlormethyl-sulfon
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Highly Enantioselective Hydrogenation of Aromatic-Heteroaromatic Ketones
関連化学物質
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(R)-(4-Chlorophenyl)(pyridin-2-yl)methanol
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Reactions of a platinum(II) agostic complex: Decyclometalation, dicyclometalation, and solvent-switchable formation of a rollover complex
関連化学物質
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[(2-tert-butyl-6-(4-fluorophenyl)pyridine(-2H))Pt(PPh3)]
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Lipase-mediated kinetic resolution of cis-1,2-indandiol and the Ritter reaction of its mono-acetate
関連化学物質
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(1R,2S)-2-acetoxy-1-indanol
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Kinetic resolution of mandelate esters via stereoselective acylation catalyzed by lipase PS-30
関連化学物質
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(3-bromo-phenyl)-hydroxy-acetic acid methyl ester
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Efficient Stereoselective Synthesis of Structurally Diverse γ- and δ-Lactones Using an Engineered Carbonyl Reductase
関連化学物質
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(R)-4-Hydroxy-nonanoic acid
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An antibody-catalyzed selenoxide elimination
関連化学物質
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Benzene, 1-methoxy-4-[2-[(4-nitrophenyl)seleninyl]propyl]-
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Chemoenzymatic synthesis of enantiopure hydroxy sulfoxides derived from substituted arenes
関連化学物質
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1H-Inden-1-ol, 2,3-dihydro-2-(phenylthio)-, trans-
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2-Arylpropionyl chlorides in kinetic resolution of racemic 3-methyl-2,3-dihydro-4H-[1,4]benzoxazines
関連化学物質
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N-[(2S)-2-(4-isobutylphenyl)propionyl]-7,8-difluoro-(3S)-3-methyl-2,3-dihydro-4H-[1,4]benzoxazine
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Kinetic resolution of heteroaryl β-hydroxy sulfides catalyzed by Humicola lanuginosa lipase
関連化学物質
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1-(pyridin-2-ylsulfanyl)propan-2-one
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Silylation-based kinetic resolution of monofunctional secondary alcohols
関連化学物質
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C29H28O2Si
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Synthesis of optically active amino acid derivatives via dynamic kinetic resolution
関連化学物質
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L-2-(4-fluoro-phenyl)-2-(2-methoxy-acetylamino)-acetamide
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Steric effects in the enantioselective transfer hydrogenation of 2- aroylacetates
関連化学物質
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(-)-3-hydroxy-3-(4-chlorophenyl)propionic acid ethyl ester
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Utilization of biocatalytic promiscuity for direct Mannich reaction
関連化学物質
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C18H21NO2
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