反応機序
この反応は通常β−アミノアクリルアミドがフタル酸ジイソプロピルエステルで酸化されることから始まる。この酸化過程は中間化合物の形成を引き起こす可能性がある。 反応の重要なステップは中間体の分子内環化に関する。β−アミノ基とアクリルアミド基を同一分子内で反応させ，イソオキサゾールと2 H−アジリジンを形成する。
化学原料を購入する必要がある場合は、 要求情報を送信してください最新の見積りを入手してください。
反応機序の学術論文
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Oxidative Cyclization of β-Aminoacrylamides Mediated by PhIO: Chemoselective Synthesis of Isoxazoles and 2 H-Azirines
関連化学物質
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N-(4-CHLOROPHENYL)-3,5-DIMETHYL-4-ISOXAZOLECARBOXAMIDE
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One-step synthesis of 1-halo-1,3-butadienes via ruthenium-catalysed hydrohalogenative dimerisation of alkynes
関連化学物質
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(1Z,3E)-1-chloro-1,4-di(4-methoxyphenyl)buta-1,3-diene
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Low-temperature n-butyllithium-induced rearrangement of allyl 1,1-dichlorovinyl ethers
関連化学物質
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((Z)-41-(2,2-dichlorovinyloxy)but-2-enyloxy)(tert-butyl)diphenylsilane
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Asymmetric synthesis of a β-lactam framework via the conjugate addition of amidocuprates(I) to chiral enoates
関連化学物質
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(R,E)-3-benzylamino-5-phenyl-4-penten-1-ol
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Reactions involving Fluoride Ion. Part 23. Thermolytic Defluorination of Perfluoroalkenes in the Synthesis of Fluorinated Dienes and Cyclobutenes
関連化学物質
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perfluoro-(3-methylbuta-1,2-diene)
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Electron-transfer substitution reactions: The p-nitrocumyl system
関連化学物質
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Pyrrolidine, 1-[1-methyl-1-(4-nitrophenyl)ethyl]-
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Regio- and stereo-selective intermolecular [2+2] cycloaddition of allenol esters with C60 leading to alkylidenecyclobutane-annulated fullerenes
関連化学物質
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1-phenylhept-2-ynyl pivalate
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Catalytic, enantioselective synthesis of α-aminonitriles with a novel zirconium catalyst
関連化学物質
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()-2-amino-4-methylvaleramide
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Transition-metal-free tunable chemoselective nfunctionalization of indoles with ynamides
関連化学物質
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ethynyl(phenyl)carbamic acid tert-butyl ester
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An efficient approach to fused indolines via a copper(I)-catalyzed reaction of sulfonyl azide with 2-ethynylaryl methylenecyclopropane
関連化学物質
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7-methoxy-1-tosyl-2,3-dihydro-1H-benzo[f]indole
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Citric acid as a trifunctional organocatalyst for thiocyanation of aromatic and heteroaromatic compounds in aqueous media
関連化学物質
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硝酸二アンモニウムセリウム(IV)
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3-Bromo-4-thiocyanatoaniline
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REDOX-DEMERCURATION OF PHENYLMERCURY 4-FLUOROTHIOPHENOXIDE BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
関連化学物質
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trans-4-fluorophenylbis(triphenylphosphine)platinum thiophenoxide
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Stereochemical and regiochemical studies on the alkylation of pentane-2,4-dione through its Co(II) complex
関連化学物質
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5-methylcyclohex-2-enyl chloride
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Copper-catalyzed synthesis of purine-fused polycyclics
関連化学物質
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3-benzyl-3H-benzo[4,5]imidazo[2,1-i]purine
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Reaction of electron-deficient N-sulfinylanilines with chiral α-hydroxy acids: A new process for the synthesis of enantiomerically pure α-hydroxy amides
関連化学物質
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Benzenamine, 2,4-dichloro-N-sulfinyl-
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Rates of decarboxylation of acyloxy radicals formed in the photocleavage of substituted 1-naphthylmethyl alkanoates
関連化学物質
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Naphthalene, 1-(2,2-dimethylpropyl)-
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Homogeneous catalytic hydrosilylation of the C=C double bond with platinum catalysts
関連化学物質
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methyl 2-methyl-3-triphenylsilylpropionate
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Reaction of Olefins with Malonic Acid Derivatives in the Presence of Manganese(III) Acetate
関連化学物質
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2-bromo-4-phenyl-4-butanolide
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CuCl2-catalyzed highly stereoselective and chemoselective reduction of alkynyl amides into α,β-unsaturated amides using silanes as hydrogen donors
関連化学物質
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2-Propynamide, N-methoxy-N-methyl-3-phenyl-
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Palladium-catalyzed oxidative cyclizations: Synthesis of dihydropyranones and furanones
関連化学物質
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3(2H)-Furanone, 5-(4-methoxyphenyl)-2,2-dimethyl-
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Further studies on the cyclisation of 3-hydroxy-2'-nitrodiphenyl ethers and related compounds
関連化学物質
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塩化アンモニウム
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4
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10H-Phenoxazin-3-aMine
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The vicinal functionalization of olefins: A facile route to the direct synthesis of β-chlorohydrins and β-chloroethers
関連化学物質
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(RS:3RS)-2-chloro-3-methoxy-3-phenyl-propionic acid
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Conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds catalyzed by a cationic rhodium complex
関連化学物質
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5-Decen-2-one, 4-phenyl-, (5E)-
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Intramolecular O-arylation of phenols with phenylboronic acids: Application to the synthesis of macrocyclic metalloproteinase inhibitors
関連化学物質
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(2S,3R)-2-[3-(4-Benzyloxy-phenyl)-propyl]-3-[(S)-2-(4-iodo-phenyl)-1-methoxycarbonyl-ethylcarbamoyl]-5-methyl-hexanoic acid tert-butyl ester
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Modelling Radical-initiated DNA Cleavage by Vinyl Epoxides
関連化学物質
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2-<2-(tert-butyldiphenylsiloxy)ethoxy>ethyl 2,3-epoxypent-4-enyl ether
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The coupling of arylboronic acids with nitroarenes catalyzed by rhodium
関連化学物質
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C14H12O(18)O
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The novel reaction of ketones with o-oxazoline-substituted anilines
関連化学物質
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2-(4,5-DIHYDRO-4,4-DIMETHYLOXAZOL-2-YL)BENZENAMINE
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Lanthanum(III) nitrate hexahydrate or p-toluenesulfonic acid catalyzed one-pot synthesis of 4(3H)-quinazolinones under solvent-free conditions
関連化学物質
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4(3H)-Quinazolinone, 3-(2-fluorophenyl)-
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Kinetic study of axial ligand substitution in (tetraphenylporphinato)chromium(III) chloride
関連化学物質
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トルエン
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[Cr(5,10,15,20-tetraphenylporphinate)Cl(1-methylimidazole)]
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Selective Base-Catalyzed Rearrangement of Epoxides into Ketones. Application to γ-Keto Sulfide Synthesis
関連化学物質
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cis-2-((phenylthio)methyl)-5-methylcyclohexanone
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KINETICS OF THE N OXIDATION OF SOME COMPOUNDS OF THE PYRIDINE SERIES WITH PERBENZOIC ACID IN CHLOROFORM AND AQUEOUS DIOXANE
関連化学物質
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Oxirane, 2-(4-chlorophenyl)-3-phenyl-, (2S,3S)-
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Trapping the oxyallyl cation intermediate derived from the Nazarov cyclization of allenyl vinyl ketones with nitrogen heterocycles
関連化学物質
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tert-butyl 2-((2-methyl-3-oxo-5-phenylcyclopent-1-enyl)methyl)-1H-pyrrole-1-carboxylate
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Cobalt-Catalyzed Photochemical Carbonylation of Allylic Amines
関連化学物質
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(E)-Pent-3-enoic acid ((E)-but-2-enyl)amide
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Studies on the bisoxazoline- and (-)-sparteine-mediated enantioselective addition of organolithium reagents to imines
関連化学物質
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Benzenemethanamine, a-butyl-, (R)-
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Hydrazidohydroxylation of styrenes with N-acetylaminophthalimide using phenyliodine(III) bis(trifluoroacetate) (PIFA)
関連化学物質
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1-(4-chlorophenyl)-2-[N-(1,3-dioxoisoindolin-2-yl)acetamido]ethyl 2,2,2-trifluoroacetate
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Nickel-catalyzed allylic substitution of simple alkenes
関連化学物質
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(E)-1-methoxy-4-(penta-1,4-diene-1-yl)benzene
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REDUCTIVE PINACOL-TYPE REARRANGEMENT OF GHIRAL α-MESYLOXY KETONES PROMOTED BY ORGANOALUMINIUM COMPOUNDS
関連化学物質
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1-Propanone, 2-(1-ethoxyethoxy)-1-phenyl-
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Structural effects on interconversion of oxygen-substituted bisketenes and cyclobutenediones
関連化学物質
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3-Cyclobutene-1,2-dione, 3,4-bis(4-nitrophenoxy)-
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Rhodium(II)-Catalyzed Formal [3 + 2] Cycloaddition of N-Sulfonyl-1,2,3-triazoles with Isoxazoles: Entry to Polysubstituted 3-Aminopyrroles
関連化学物質
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5-butyl-3-(4-chlorophenyl)isoxazole
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Reactions of N- or N'-Blocked N-acylureas with Amines
関連化学物質
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N-フェニルホルムアミド
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Gold(i)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination
関連化学物質
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4-(cyclohexylmethyl)-4-vinyl-1,2,3-oxathiazinane 2,2-dioxide
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Metal-Free Electrophilic Alkynylation of Sulfenate Anions with Ethynylbenziodoxolone Reagents
関連化学物質
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1-methyl-4-[(2-nitroethyl)sulfanyl]benzene
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Conjugate Addition of Diboron Catalyzed by O -Monoacyltartaric Acids
関連化学物質
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(S)-3-hydroxy-1-(4’-methoxylphenyl)-3-phenylpropan-1-one
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Bis(phosphinite) with C2-symmetric axis; Effects on the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of acetophenone derivatives
関連化学物質
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(2S)-2-[benzyl(2-{benzyl[(1S)-2-hydroxy-1-phenylethyl]amino}ethyl)amino]-2-phenylethan-1-ol
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Conversion of bromoalkenes into alkynes by wet tetra-n-butylammonium fluoride
関連化学物質
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4-bromo-5-phenylpent-4-en-1-ol
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Indirect electrochemical oxidation of cyclic ketones: Influence of ring size, mediator and supporting electrolyte on the result of the reaction
関連化学物質
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1-Cycloundecene-1-carboxylic acid, methyl ester, (E)-
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