反応機序
この反応は通常β−アミノアクリルアミドがフタル酸ジイソプロピルエステルで酸化されることから始まる。この酸化過程は中間化合物の形成を引き起こす可能性がある。 反応の重要なステップは中間体の分子内環化に関する。β−アミノ基とアクリルアミド基を同一分子内で反応させ，イソオキサゾールと2 H−アジリジンを形成する。
化学原料を購入する必要がある場合は、 要求情報を送信してください最新の見積りを入手してください。
反応機序の学術論文
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The coupling of arylboronic acids with nitroarenes catalyzed by rhodium
関連化学物質
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C14H12O(18)O
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Mitsunobu reaction of 1,2,3-NH-triazoles: A regio- and stereoselective approach to functionalized triazole derivatives
関連化学物質
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2-allyl-4-phenyl-5-(1-phenylvinyl)-2H-1,2,3-triazole
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STEREOSELECTIVE SYNTHESIS OF SOME CIS 2,3-DISUBSTITUTED CYCLANONES RING SIZE INFLUENCE ON THE STEREOSELECTIVITY OF 2-SUBSTITUTED ENDOCYCLIC ENOLATES PROTONATION
関連化学物質
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cis-2-methyl 3-phenylthiocyanomethyl cyclohexanone
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A novel method for the synthesis of telluroesters
関連化学物質
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2-Bromo-tellurobenzoic acid Te-phenyl ester
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Cerium trichloride
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Kinetics of the formation of N-arylsydnones from N-nitroso-N-arylglycines.
関連化学物質
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[(4-chlorophenyl)(nitroso)amino]acetic acid
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A Novel Synthesis of 4-Propyl-2H-1-benzopyran-2-ones
関連化学物質
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5,7-DIMETHOXY-4-PROPYL-CHROMEN-2-ONE
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SYNTHESIS AND DECOMPOSITION OF E- AND Z-3,3,5-TRISUBSTITUTED 1,2-DIOXOLANES.
関連化学物質
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1,3-Diphenyl-pentandiol-(1,3)
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Synthesis of fluoro-containing pyrimidinones from hexafluoroacetone(ethoxycarbonylimine)
関連化学物質
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1-(4-methylphenyl)-5,5-bis(trifluoromethyl)-5,8-dihydro-1H,6H-pyrimido[4,5-d]pyrimidine-2,4,7-trione
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Synthesis of 6-aryl-4,5-dibenzamido-1,2,3,6-tetrahydropyridines
関連化学物質
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5-methyl-4-(4-methoxyphenyl)-4,5,6,7-tetrahydro-1H-imidazo<4,5-c>pyridine
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REACTION OF 2-AMINO-5-R-PHENYL-1,3,4-THIADIAZOLES WITH UNSATURATED ACIDS AND ACID CHLORIDES
関連化学物質
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N-<5-(4-Chlorophenyl)-1,3,4-thiadiazol-2-yl>acrylamide
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Triazolines. 19. Nickel Peroxide Oxidation of Δ2-1,2,3-Triazolines. A Versatile General Synthetic Route to 1H-1,2,3-Triazoles
関連化学物質
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Pyridine, 2-[1-(3,4-difluorophenyl)-1H-1,2,3-triazol-5-yl]-
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4-Substituted-1,2,3,4-tetrahydro-3,3-dimethylisoquinolines. II. (1)
関連化学物質
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α-<1-<(3-methoxyphenylmethyl)amino>-1-methylethyl>benzenemethanol
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Thioimidate Methylides by the Desilylation Method: An Improved Synthesis of Pyrrolines and Pyrroles
関連化学物質
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2-Piperidinethione, 1-[(trimethylsilyl)methyl]-
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Addition of Glycinate Enolate Equivalents to 1,4-Benzodiazepine Imino Phosphates. Preparation of Synthetically Useful 2-(Ethyl glycinat-α-ylidene)-1,4-benzodiazepines and Related Derivatives
関連化学物質
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4H-Imidazo[1,5-a][1,4]benzodiazepine-3-carboxylicacid, 8-chloro-6-phenyl-, ethyl ester
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Areneselenolate-mediated perfluoroalkyl-sulfenylation of enol ethers
関連化学物質
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1-Methoxy-4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-isobutoxy-octylsulfanyl)-benzene
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A CONVENIENT SYNTHESIS OF 5-ETHOXY-4-(TRIFLUOROMETHYL)-2-OXAZOLECARBOXYLIC ACID AND RELATED TRIFLUOROMETHYL SUBSTITUTED HETEROCYCLIC COMPOUNDS
関連化学物質
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5-Ethoxy-4-trifluoromethyl-oxazole-2-carboxylic acid phenyl ester
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Aerobic Conversion of Organic Halides to Alcohols. An Oxygenative Radical Cyclization
関連化学物質
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4-Benzyloxy-5-methyl-hex-1-en-3-ol
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THE REACTION OF A PHOSPHAALKENE WITH ORTHOQUINONES
関連化学物質
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C33H19Cl8O4P
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Synthesis of the 11-(Hydrogen Succinate) and 11-(β-D-Glucopyranosiduronic Acid) Derivative of Estra-1,3,5(10)-triene-3,11α,17β-triol
関連化学物質
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1,3,5(10)-ESTRATRIEN-3,11-ALPHA, 17-BETA-TRIOL 11-HEMISUCCINATE
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Synthesis of fluorescent 5-(2-hydroxyaryl)-7-substituted-2,3-dihydro-1H-1,4-diazepines and related fluorescent 1,5-benzodiazepines
関連化学物質
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5-(2-Methoxyphenyl)-7-phenyl-2,3-dihydro-1H-1,4-diazepine
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Chemistry of 1,2,4-triazines; XIII. Synthesis of 1H-[1,2,4]triazino [5,6-e][1,3,4]thiazidazines and 1,2,4-triazolo[4,3-d][1,2,4]triazines
関連化学物質
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5-Hydrazino-3-p-tolyl-[1,2,4]triazin-6-ylamine
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Palladium-Catalyzed Cross-Carbonylation of Aryl Iodides and 1-Aryl-2-alkyn-1-ones
関連化学物質
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3-benzoyl-2-ethyl-5-phenylfuran
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The Conversion of Carboxylic Acids to Keto Phosphorane Precursors of 1,2,3-Vicinal Tricarbonyl Compounds
関連化学物質
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Benzenepropanoic acid, b-oxo-a-(triphenylphosphoranylidene)-, 1,1-dimethylethyl ester
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Thermolysis of O-allyl S-alkyl dithiocarbonates of codeine and isocodeine.
関連化学物質
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C26H27NO3S2
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Stereospecific decarboxylative allylation of sulfones
関連化学物質
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(S)-1-chloro-4-(2-(phenylsulfonyl)pent-4-en-2-yl)benzene
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Use of the graebe-ullmann reaction in the synthesis of 8-methyl-γ- carboline and isomeric aromatic aza-γ-carbolines
関連化学物質
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N4-(4-methylphenyl)-3,4-Pyridinediamine
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Intermolecular cyclopropanation versus CH insertion in Rh(II)-catalyzed carbenoid reactions
関連化学物質
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2,6-di-tert-butyl-4-methylphenyl (cyclohexen-3-yl)acetate
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Metalation reactions XIII. The reactions of electrophiles with the dilithiated species 1-(α-lithiomethyl)-2-<(α-lithiomethyl)thio>benzene
関連化学物質
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1-Ethyl-2-(ethylthio)benzene
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A convenient synthesis of vinyl epoxides from glycidic esters via α-hydroxy-β,γ-unsaturated esters
関連化学物質
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1-(4-Methyl-cyclohex-1-enyl)-ethane-1,2-diol
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SYNTHESIS AND REACTIONS OF ORGANYL CHLOROETHYL SULFIDES WITH PHOSPHORUS-CONTAINING NUCLEOPHILES
関連化学物質
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Benzene, [(chloroethynyl)thio]-
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Palladium-catalyzed allylic oxidation of 1-(p-toluenesulfonyl)-2-propene and 1-(trimethylsilyl)-1-(p-toluenesulfonyl)-2-propene
関連化学物質
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2-Propenal, 3-[(4-methylphenyl)sulfonyl]-, (E)-
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Addition of Phenols to Perfluorovinyl Ethers. Protonation and Halogenation of Carbanionic Intermediates
関連化学物質
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Benzene, [2-chloro-1,1,2-trifluoro-2-(heptafluoropropoxy)ethoxy]-
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On the synthesis of 2-(1-hydroxybenzyl)-3-phenyl-1,3-oxazolidine
関連化学物質
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1-(acetyloxy)cyclohexanecarboxaldehyde
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Cyclocondensation of Alkylhydrazines and β-Substituted Acetylenic Esters: Synthesis of 3-Hydroxypyrazoles
関連化学物質
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1-メチル-5-フェニル-1H-ピラゾール-3-オール
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Pd/PTABS: Catalyst for Room Temperature Amination of Heteroarenes
関連化学物質
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2-chloro-4-(4-tosylpiperazin-1-yl)pyrimidine
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Thermal activation of hydrocarbon C - H bonds by tungsten alkylidene complexes
関連化学物質
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W(C5(CH3)5)(NO)(CH2C6H5)(CH2Si(CH3)3)
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STEREOSELECTIVITY IN FREE RADICAL REACTIONS
関連化学物質
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2-(Pyridin-2-ylsulfanyl)-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
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STUDIES OF PYRIDAZINE COMPOUNDS, XXV. REINVESTIGATION OF ACYLATION OF PYRIDAZINYLHYDRAZONES
関連化学物質
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2-(4-chlorobenzoyl)-3-methyl-6-morpholino-3-(tertiary butoxycarbonylmethyl)-2,3-dihydro-1,2,4-triazolo<4,3-b>pyridazine
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Synthesis of pyrrole derivatives by palladium-catalyzed cyclization of γ,δ-unsaturated ketone o-pentafluorobenzoyloximes
関連化学物質
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4-Penten-1-one, 1-phenyl-, O-(pentafluorobenzoyl)oxime, (1E)-
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Diazotetrakis(trifluoromethyl)cyclopentadiene and Ylides of Electronegative Elements
関連化学物質
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2,4-Bis-(4-fluoro-phenyl)-6,7,8,9-tetrakis-trifluoromethyl-1,3-diaza-spiro[4.4]nona-1,3,6,8-tetraene
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Diastereoselective Ring-Opening Aldol-Type Reaction of 2,2-Dialkoxycyclopropanecarboxylic Esters with Carbonyl Compounds. 1. Synthesis of Cis 3,4-Substituted γ-Lactones
関連化学物質
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4,4-Dimethyl-5-oxo-2-phenethyl-tetrahydro-furan-3-carboxylic acid ethyl ester
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1,1-dihydroperfluoroalkylations of nucleophiles with (1,1-dihydroperfluoroalkyl)phenyliodonium triflates
関連化学物質
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Benzyldimethyl(2,2,2-trifluoroethyl)ammonium triflate
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N,N-Dimethylformamide (DMF) as a Source of Oxygen to Access α-Hydroxy Arones via the α-Hydroxylation of Arones
関連化学物質
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1-Propanone, 2-hydroxy-1-(4-methoxyphenyl)-
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Proton-Transfer Reactions. 4. Near-Unity Kinetic Isotope Effects for Hydron Exchange and Dehydrofluorination Reactions
関連化学物質
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1,1,1,3,3,3-ヘキサフルオロ-2-フェニルプロパン
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A General Route to N(SCl)2+ and SNS+ Salts
関連化学物質
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{C6H5CNSNS}(1+)*AsF6(1-)={C6H5CNSNS}{AsF6}
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